When a crystal breaks, it means the forces acting upon it have exceeded its mechanical strength, causing the atomic bonds holding its structure together to rupture.
Here's a breakdown of what's happening:
Stress and Strain: Crystals, like any material, experience stress when subjected to external forces (pressure, tension, shear, etc.). This stress causes strain, which is the deformation of the crystal lattice.
Crack Propagation: The fracture often starts at a point of weakness, such as a surface flaw, inclusion, or grain boundary (in polycrystalline materials). The stress concentrates at this point. When the stress exceeds the critical stress intensity factor, a crack begins to propagate.
Cleavage: Many crystals break along specific planes called cleavage planes. These planes are directions of weaker atomic bonding within the crystal lattice. The break will be relatively smooth and follow these planes.
Fracture Surface: The resulting fracture surface provides information about the breaking mechanism. Different patterns and textures can reveal the direction of crack propagation and the type of stress that caused the failure. The study of fracture surfaces is called fractography.
Types of Fracture: Fracture can be broadly classified as brittle fracture (rapid crack propagation with little plastic deformation) or ductile fracture (slow crack propagation with significant plastic deformation). Crystals typically exhibit brittle fracture due to their limited ability to deform plastically.
Factors Affecting Breaking: Several factors influence how a crystal breaks, including:
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